A Level H2 Chemistry – Bonding

April 11, 2016 A Level Chemistry 0

A-Level Chemistry: Chemical Bonding

1.) Why Xenon Tetrafluoride has a square planar shape?
(Explained By VSEPR theory)

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2.) What is Hydrogen bonding in water? (Explanation on the open structure of water)

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A water molecule can form a maximum of four hydrogen bonds because it can accept two and donate two hydrogen atoms. Other molecules like hydrogen fluoride, ammonia, methanol form hydrogen bonds but they do not show anomalous behaviour of thermodynamic, kinetic or structural properties like those observed in water. The answer to the apparent difference between water and other hydrogen bonding liquids lies in the fact that apart from water none of the hydrogen bonding molecules can form four hydrogen bonds either due to an inability to donate/accept hydrogens or due to steric effects in bulky residues. In water local tetrahedral order due to the four hydrogen bonds gives rise to an open structure and a 3-dimensional bonding network, resulting in the anomalous decrease of density when cooled below 4 C.
Although hydrogen bonding is a relatively weak attraction compared to the covalent bonds within the water molecule itself, it is responsible for a number of water’s physical properties. One such property is its relatively high melting and boiling point temperatures; more energy is required to break the hydrogen bonds between molecules. The similar compound hydrogen sulfide (H2S), which has much weaker hydrogen bonding, is a gas at room temperature even though it has twice the molecular mass of water.